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Mww-Type Titanosilicate
Synthesis, Structural Modification and Catalytic Applications to Green Oxidations
Peng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He
Livre broché | Anglais | SpringerBriefs in Molecular Science | SpringerBriefs in Green Chemistry for Sustainability
52,95 €
+ 105 points
Description
This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.
Spécifications
Parties prenantes
- Auteur(s) :
- Editeur:
Contenu
- Nombre de pages :
- 125
- Langue:
- Anglais
- Collection :
Caractéristiques
- EAN:
- 9783642391149
- Date de parution :
- 20-08-13
- Format:
- Livre broché
- Format numérique:
- Trade paperback (VS)
- Dimensions :
- 150 mm x 229 mm
- Poids :
- 204 g
